邓桃;杨滴;陶文彪;周凯;张学军;谷琛;

• 1:中国电力科学研究院
• 2:四川大学电气信息学院

摘要(Abstract)：

为研究粉化硅橡胶伞裙的憎水性与其微观结构的关系,针对现场取回的3支粉化的110kV复合绝缘子,通过红外光谱、扫描电镜、能谱分析等方法开展研究。首先,利用静态接触角和喷水分级法测试样本的憎水性,粉化层表面的憎水性相比新样本略有下降,去掉表面的粉化层后,其憎水性明显下降。然后,通过红外光谱测试发现样本的主链和侧链基团(Si-O和Si-CH_3)发生了断裂,侧链甲基含量减少;扫描电镜发现去粉化层后硅橡胶表面存在大量微孔和裂纹,因而导致去粉化层后的硅橡胶伞裙表面憎水性明显降低。最后,通过能谱分析发现,粉化层中的硅含量明显高于去粉化层后硅橡胶表面和材料内部值,同时粉化层表面的粗糙度增加,说明粗糙度和硅氧烷小分子的迁移同时导致粉化层表面的憎水性优于去掉粉化层后的表面。研究结果表明,粉化与硅橡胶伞裙的憎水性关联密切,但仍需深入研究粉化复合绝缘子的运行可靠性和使用寿命。

关键词(KeyWords)： 复合绝缘子;粉化;憎水性;红外光谱;扫描电镜;能谱分析

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 邓桃;杨滴;陶文彪;周凯;张学军;谷琛;

Email:

DOI: 10.13335/j.1000-3673.pst.2016.01.046

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